Synthesis and Characterization of Chlorinated Bisphenol-Based Polymers and Polycarbodiimides as Inherently Fire-Safe Polymers

Details

• Creators:
  Stewart, Jennifer R.
• Corporate Creators:
  University of Massachusetts at Amherst. Polymer Science and Engineering Department
• Contributors:
  Lyon, Richard
• Subject/TRT Terms:
  Bisphenol-C Calorimeters Combustion Fire Flammability Polycarbodimides Polymers Thermal Degradation
• Publication/ Report Number:
  DOT/FAA/AR-00/39
• Resource Type:
  Tech Report
• Geographical Coverage:
  United States
• Edition:
  Final Report
• Corporate Publisher:
  United States. Department of Transportation. Federal Aviation Administration. Office of Aviation Research
• Abstract:
  Two different types of polymers were synthesized and their degradation and combustion behavior were investigated. The first class, 1,1-dichloro-2,2-(4-hydroxyphenyl)ethylidene (bisphenol C) based polymers, were found to be among the most fire- resistant polymers with peak heat release capacities as low as 20 J/g-K. Polymers containing bisphenol C all exhibited exothermic decomposition behavior. When compared to corresponding bisphenol-A-based polymers, these bisphenol-C- containing polymers had higher char yields and lower decomposition temperatures. The presence of bisphenol C in materials, whether as a co-monomer or blends, showed a char enhancement effect; yielding higher char than what is expected by a purely additive effect.
• Format:
  PDF
• Collection(s):
  FAA Fire Safety
• Main Document Checksum:
  urn:sha-512:b13f8222ebec7fa84885aa952f52e4162571422fb2f957d5dad236f86cb3e48768e88a19b634f3f698899f701b9d8972265fe350529ce9a47975d6c9b1f7f9a2
• Download URL:
  https://rosap.ntl.bts.gov/view/dot/92722/dot_92722_DS1.pdf
• File Type:
  [PDF - 5.67 MB ]