Thermal Dynamics of Bomb Calorimeters
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2016-04-01
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Abstract:The validated solution to a two-term heat transfer model of a bomb calorimeter allows direct calculation of the heat released in an arbitrary process from the recorded temperature history without the need to correct for non-adiabatic behavior. The heat transfer coefficients and thermal capacities of the bomb calorimeter used in the heat calculation are determined parametrically from the temperature response to a known heat impulse (i.e., benzoic acid combustion). This methodology allows accurate measurement of heat released intermittently or during an extended period of time in a bomb calorimeter, as occurs during electrical resistance heating and subsequent thermal runaway of lithium ion batteries.
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Main Document Checksum:urn:sha-512:447f71a52f43c3bbc7c950f7514932257d6101300a05bc24009715ded0ecfc3d0f44ce2f205bedc1055066b7d4dc975716d257cb708a5adb416ac94dddbe6d3f
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