United States Department of Transportation
i
An Evaluation of Parameters Pertinent to Dry Ice Sublimation
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2024-10-01
[PDF-1.42 MB]
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Abstract:As a result of the COVID-19 (SARS-CoV-2) pandemic, over 12.7 billion vaccine doses were shipped and administered across 184 countries. Transportation via aircraft was a significant contributor in this effort. Many of the COVID-19 vaccines need to be stored at extremely low temperatures to maintain efficacy, therefore, dry ice has been used as a method to keep vaccines refrigerated throughout air shipments. Dry ice is categorized as a Class 9 (Miscellaneous) Dangerous Good. Dry ice undergoes a process called sublimation at normal pressure and temperatures, in which the solidified form transitions directly to gaseous CO2. This process can create an oxygen deficient environment in confined areas (including aircraft), which can produce shortness of breath, unconsciousness, or death if exposed over prolonged periods of time. An assessment was conducted by the Federal Aviation Administration (FAA) to identify parameters pertinent to dry ice sublimation throughout air shipment. This study was motivated by minor sublimation rates (<1% per hour) claimed from container manufacturers. This has important safety implications as decreases in sublimation rates allow for exponential increases in permitted dry ice cargo. Further analysis was needed. Specifically, this study evaluated the following parameters’ impact: temperature, pressure, humidity, dry ice pellet size, container design and durability. Results indicate that dry ice pellet size, container design, and durability had a clear impact on sublimation rate. Sublimation rates differed significantly between the three containers evaluated within this study and were observed to increase as containers were reused. Furthermore, dry ice pellets with smaller nominal diameters were noted to sublimate at a higher rate than those with a larger diameter. Other evaluated parameters within this study produced no clear correlation. Although sublimation was observed to be affected by numerous parameters, data suggests a conservative approach to this subject is prudent. While some external conditions may produce only minor differences in sublimation rates, it would have a major impact on the allowable quantity of dry ice shipped.
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