Impact of cold climates on vehicle emissions: the cold start air toxics pulse : final report.
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2016-09-21
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Edition:Final report
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Abstract:This project measured cold start emissions from four vehicles in winter using fast response instrumentation to accurately measure the ; time variation of the cold start emission pulse. Seventeen successful tests were conducted over a temperature range of -4°C to 10°C in ; winter 2015 at the Washington State University campus. Vehicle cold starts are thought to be a significant source of air toxic ; compounds in cold winter environments due to the rapid increase in mass emission rates with decreasing temperature. We used a ; proton transfer reaction mass spectrometer for high time resolution measurement of the emissions the air toxic compounds benzene, ; formaldehyde, acetaldehyde, in addition to toluene and C2-alkylbenzenes. Measured molar emission ratios relative to toluene in the ; cold start pulse were compared with cold start emission profiles for E10 fueled vehicles used in the EPA MOVES2014 model. We found ; that the measured acetaldehyde-to-toluene emission ratio was about a factor of 8 greater than the emission ratio used in ; MOVES2014. Measured formaldehyde-to-toluene emission ratios were a factor of 5 greater. Our study suggests that emission of the ; air toxics acetaldehyde and, likely, formaldehyde is significantly underestimated in wintertime by the MOVES2014 model.
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Main Document Checksum:urn:sha256:34a81c65729ed19314b1040552d6a269716bf7e8409ef639e96a299eef00bffb