Study of Low-Temperature Active Rare-Earth Oxide Catalysts for Automotive Exhaust Clean-Up
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2014-02-02
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Abstract:We report a facile oneāpot synthesis of CexZr1-xO2 (0x1) solid solution nanocrystals using hydrothermal reactions. A direct formation of oxide solid solutions in aqueous solution under pressure at low temperatures was clearly revealed by X-ray diffraction, Raman spectroscopy, and chemical composition analysis of individual nanocrystals using energy dispersive X-ray spectroscopy in scanning transmission electron microscopy mode. Chemisorption behavior of the synthesized nanocrystals was characterized using hydrogen temperature programmed reduction, which showed a superior low-temperature activity in CexZr1-xO2 (0
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