Responsible Use of Polyphosphoric Acid (PPA)
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2023-02-01
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Edition:Final Report
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Abstract:Polyphosphoric acid (PPA) is a chemical modifier employed to improve high temperature rheological properties without adversely affecting low temperature rheological properties that has been used since the early 1970s.(1) Implementation of Superpave performance-grade (PG) asphalt binder acceptance specifications lead to use of PPA to aid in meeting rheological parameters of some polymer modified asphalt binders. PPA has also been used as a binder modifier to extend the asphalt binder range between the high and low temperature performance limits of the specification. This report provides information to supplement existing publications communicating responsible use of Polyphosphoric Acid (PPA) in asphalt binder formulations. Information is provided on current uses of PPA, available qualitative and quantitative methods to detect presence of phosphorus in asphalt binders, and suggestions as to how phosphorus might indicate the presence and amount of PPA in asphalt binders.
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