Effects of portland cement particle size on heat of hydration.
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Effects of portland cement particle size on heat of hydration.

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    • Abstract:
      Following specification harmonization for portland cements, FDOT engineers reported signs of

      deterioration in concrete elements due to temperature rise effects. One of the main factors that affect

      concrete temperature rise potential is the heat generated by portland cement during hydration. This study

      was initiated to identify the effect of cement fineness on the heat generated by portland cement. Eleven

      cements were selected for this study to address the effects of cement fineness and mineralogy. Several

      of the cements came from the same source but had different grinds. This was important in studying the

      fineness contribution to heat of hydration while maintaining similar cement mineralogy. The as-received

      cements from different suppliers had a wide range of mineralogical compositions which allowed the

      study of the effects of mineralogy on the heat of hydration. Cements were characterized through oxide

      chemical analysis, x-ray diffraction, Blaine fineness, laser particle size analysis, setting behavior, and

      strength measurements. Additionally, limited restrained shrinkage experiments were performed on two

      of the cements from the same source to determine the effect of cement fineness on restrained shrinkage.

      The findings indicate that cement fineness is better correlated to 7-day heat of hydration than the heat

      index expressed as C3S + 4.75 C3A. Additionally, the results indicate that a finer cement experiences

      higher shrinkage than a coarser cement. Comparison of activation energies indicates that cements with

      higher fineness have lower activation energy. For Type II moderate heat (MH) portland cements that

      will be used in structural concrete elements where there is a risk of cracking due to thermal stresses, it

      is recommended that limits be placed on the heat of hydration, the Blaine fineness, and the heat index.

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