Laboratory and field studies of photocatalytic NOx and O3 removal by coatings on concrete.
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2017-03-01
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Abstract:This project involved thorough testing of titanium dioxide (TiO2)-containing commercial photocatalytic coatings ; applied to portland cement concrete for highway applications, focusing on the use of these coatings as an ; abatement method for atmospheric nitrogen oxide (NOx) and ozone (O3). The study consisted of four parts: ; laboratory chamber testing; outdoor exposure studies; modeling; and field application. Full-factorial experiments ; in laboratory chambers designed to examine the impact of variables such as temperature, relative humidity, time, ; and pollutant concentrations on NOx and O3 removal by the coatings demonstrated that a commercial stucco was ; the best performer of the four original materials tested. After one and two years of outdoor, roadside exposure, ; the NOx removal capacity of the stucco decreased significantly, but could be improved by soap and water ; washing. A Comprehensive Air Quality Model with extensions (CAMx) for the Houston-Galveston-Brazoria and ; Dallas-Fort Worth areas showed the potential of the stucco to reduce average ozone concentrations if large areas ; of highway structures are coated. Testing at a field site in north Austin, however, showed no conclusive ; difference between air quality in areas with coated and uncoated highway barriers. Therefore, while ; photocatalytic concrete coatings have promise for improving air quality, the data from this project suggest that ; such improvements may not be significant enough to be measured experimentally in common roadway ; configurations such as the site tested for this study.
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