Corrosion evaluation of novel coatings for steel components of highway bridges.
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Corrosion evaluation of novel coatings for steel components of highway bridges.

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      The Florida Department of Transportation (FDOT) had expressed interest in gauging the available coating

      technologies that may have suitable applications for steel components in highway bridges. The motivation was to

      possibly identify coating systems that would provide corrosion durability of steel components in highway bridges

      and reduce costs associated with regular inspection and maintenance of the coating systems. Chemically

      bonded phosphate ceramics (CBPC) and the thermal diffusion galvanizing (TDG) process have been identified

      for further testing due to growing interest in the systems for possible corrosion mitigation, the lack of sufficient

      data to determine their effectiveness for corrosion protection of steel structures, and their commercial availability.

      An issue for further evaluation of long term durability and corrosion protection by CBPC coatings is the degree

      of deterioration of the ceramic coating in aggressive environments. Initial testing showed that the material was

      not durable in highly alkaline solutions (pH 13), and in exposure conditions that cycle between frequent high

      moisture contents and drying conditions. The rather short-term outdoor exposures investigated so far have

      produced some promising results, but the significant extent of undercoating surface oxidation that was observed

      may compromise long-term durability. The intermediate alloy layer was not consistently identified and its role in

      corrosion mitigation has not been elucidated.

      Although no severe steel corrosion was observed for TDG in outdoor exposure, degradation of the topcoat,

      when present, and subsequent consumption of the TDG would result in a shorter service life of the coating for

      corrosion mitigation. Variations in quality of the topcoats resulted in variations in coating performance. The

      findings suggest that sufficient application of the TDG and robust topcoats are required for long-term durability.

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