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Influence of Changes in Water-to-Cement Ratio, Alkalinity, Concrete Fluidity, Voids, and Type of Reinforcing Steel on the Corrosion Potential of Steel in Concrete.

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  • Abstract:
    "Research on steel corrosion has demonstrated that the concentrations of chloride and hydroxide ion at the concrete/steel ; interface influence the susceptibility of the steel to corrosive attack. This study used electrochemical means and changes in mix ; design to increase the alkalinity and improve consolidation of the concrete against the steel to determine if this would increase the ; corrosion resistance of the reinforcing steel without compromising the properties of the concrete. To understand these effects ; better, the following concrete properties were evaluated: compressive strength, splitting tensile strength, modulus of elasticity, ; and length change (shrinkage). ; The evaluation involved the casting of different types of concrete samples, all of which contained artificial voids, for ; corrosion testing. These samples were composed of one of two concrete mixtures: (1) the Virginia Department of ; Transportation’s (VDOT) Class A4 General Bridge Deck Concrete with Straight Portland Cement (A4), or (2) a selfconsolidating ; concrete (SCC). Selected A4 and SCC mixtures were electrochemically treated 135 days after samples were cast. ; Some samples were left untreated and functioned as control samples. ; There were no significant differences in the concrete properties between the short-term treatment (less than 7 hr) and ; control samples tested in this study. It was determined that alkalinity, water-to-cement ratio, and steel type all influence the ; corrosion potential of reinforcing steel when reinforced concrete is subjected to saltwater. In addition, introducing small voids ; adjacent to the steel created a greater spread between the 25th and 75th percentile of the half-cell potential measurements when ; compared to locations without voids; however, these same voids have little influence on the average value measured. A study is ; underway to perform cyclical saltwater ponding on selected samples to allow for future evaluation of corrosion resistance. ; This study showed that alkalinity, water-to-cement ratio, concrete fluidity during placement, and steel type all influence ; the corrosion potential of the reinforcing steel when reinforced concrete is subjected to saltwater. The study recommended that ; the Virginia Center for Transportation Innovation and Research (VCTIR) continue performing saltwater exposure on these ; specimens until corrosion becomes evident and then autopsy them and characterize the corrosion of the steel reinforcement. In ; addition, VCTIR should work with VDOT’s Materials Division to compare various concrete mix designs that would be ; considered acceptable to VDOT and assess how each influences the corrosion potential on embedded steel. Further, more ; emphasis should be placed on mix designs, such as SCC mixtures, that could provide VDOT with greater corrosion resistance ; and reduced labor during placement."
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    Filetype[PDF - 3.59 MB]
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    urn:sha256:ac74169d52b52e371ce7de206fea59020e5fd69b03f91ec92132c6e6fc064451
File Language:
English
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