Development of an embeddable microinstrument for corrosivity monitoring in concrete.
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1999-07-01
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Edition:Final Contract, 10/96-6/99
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Abstract:The aim of this program was the development of a small and completely embeddable microinstrument for corrosivity measurement ; in concrete. It should contain all the electronics for the electrochemical measurements, the means for data transfer between engineer ; and device, and sensors sensitive to the different corrosivity parameters. The goals of the work reported here were to develop and ; test the required sensors and electronics in a laboratory setting. ; Sensors for the measurement of corrosion rate, corrosion potential, chloride concentration, and concrete conductivity were ; developed and tested in laboratory-scale concrete slabs. The tests included electrochemical chloride driving as a method for test ; acceleration and wet/dry cycling. The corrosion sensor consists of a piece of reinforcing steel as working electrode, another rebar ; piece or a platinized Nb-mesh as counterelectrode, and an Ag/AgCI electrode as reference electrode. The conductivity sensor is ; based on a modified Wenner four-pin method and made of four parallel Au wires. Both sensors work very well. Chloride ; introduced into the concrete electrochemically induced corrosion on the corrosion sensor, as seen by a decrease in potential and in ; the polarization resistance. The potentials recovered after more than 1000 h of electrochemical chloride removal, but the corrosion ; resistance did not regain its original value. The change in chloride content was monitored by a silver/silver chloride chloride sensor. ; The only present drawback of the microinstrument is the construction of a long-term reliable reference electrode. The best ; candidates seem to be Ni/W galvanic couple and lead. ; A micropotentiostat coupled to a zero-resistance ammeter and a microgalvanostat based on operational amplifiers were designed: and ; heart of a complete measurement system, which includes on two double surface mount boards the ASIC, a microprocessor, control ; circuitry, and connections to the external corrosivity sensors, as well as RF transceiver circuitry for the wireless communication with ; the instrument.
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Main Document Checksum:urn:sha256:5b2ab5ca5d8bd966dfd5edf512cc0877698420aa2702c49c20ce2783d8e24e0f